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Carbon isotopes in magmatic systems serve as powerful tracers for understanding magma evolution, mantle processes, the deep carbon cycle, and the origin of Earth’s carbon. This review provides a comprehensive overview of carbon isotope measurements and behavior in magmatic systems, highlighting recent technological advancements and scientific insights. We begin by examining methods for measuring δ13C in volcanic gases, vesicles, glasses, melt, and fluid inclusions. We then explore the behavior of carbon isotopes in magmatic systems, especially during magmatic degassing. Finally, we evaluate what recent advances mean for our understanding of the carbon isotope signature of the Earth’s upper mantle. 

Unraveling the origin(s) of carbon on Earth has remained challenging, not only because of the multiple isotopic fractionation episodes that may have occurred during planet formation processes but also because the end point of these processes, the current isotopic value of Earth’s deep carbon reservoirs remains poorly constrained. Here, we present carbon isotopic measurements on rare undegassed mid-ocean ridge basalts from the Pacific, Atlantic, and Arctic Oceans that have preserved the isotopic signature of their mantle source. We find that Earth’s present-day convecting upper mantle has variable δ¹³C value from ~−10 to −4‰, significantly different from the δ¹³C value of peridotitic diamonds and with the highest values being restricted to the Atlantic. Evidence for significant mantle heterogeneity contrasts with previous assumptions and its origin remains puzzling being uncorrelated with geochemical markers associated with either subduction and surficial recycling processes or lower mantle contributions. The data do not preclude other causes such as primordial mantle heterogeneity. We suggest that the δ¹³C value of the bulk silicate Earth may need to be revised. 

Magma ascent rate is a challenging parameter to constrain yet a crucial element to investigate magma dynamics. The 1600 eruption of the Huaynaputina volcano was the largest recorded eruption in South America, with an impact area that now hosts approximately a quarter of Peru's population. The aim of this study is to investigate the magma ascent rate of the initial Plinian phase of the eruption using pyroclast texture. Scanning electron microscopy (SEM) was employed to image several pumice clasts. The images were then cleaned and processed using the Fast Object Acquisition and Measurement System (FOAMS) to obtain a vesicle number density. Melt inclusions in crystals were identified and double polished, and their H₂O content was analyzed using infrared spectroscopy (FTIR). The mean value of the BND is 4.09×10 6 mm⁻³, while the mean value of the H₂O content is 3.05%. According to the nucleation theory, the average decompression rate is thus calculated to be 13.47 MPa/s (ascent rate of 548 m/s). An alternative equation, which relies solely on the BND, provides a decompression rate of 9.06 MPa/s (ascent rate of 362 m/s). Both calculated values are high, but remain within a reasonable range for eruptions of this magnitude. If this eruption were to occur today, it would have a catastrophic impact. These results emphasize the necessity for further research to provide a deeper understanding of such destructive eruptions. 

We present a new set of reference materials, the ND70‐series, forin situmeasurement of volatile elements (H₂O, CO₂, S, Cl, F) in silicate glass of basaltic composition. The materials were synthesised in piston cylinders at pressures of 1 to 1.5 GPa under volatile‐undersaturated conditions. They span mass fractions from 0 to 6%m/mH₂O, from 0 to 1.6%m/mCO₂and from 0 to 1%m/mS, Cl and F. The materials were characterised by elastic recoil detection analysis for H₂O, by nuclear reaction analysis for CO₂, by elemental analyser for CO₂, by Fourier transform infrared spectroscopy for H₂O and CO₂, by secondary ion mass spectrometry for H₂O, CO₂, S, Cl and F, and by electron probe microanalysis for CO₂, S, Cl and major elements. Comparison between expected and measured volatile amounts across techniques and institutions is excellent. It was found however that SIMS measurements of CO₂mass fractions using either Cs⁺or O⁻primary beams are strongly affected by the glass H₂O content. Reference materials have been made available to users at ion probe facilities in the US, Europe and Japan. Remaining reference materials are preserved at the Smithsonian National Museum of Natural History where they are freely available on loan to any researcher. 

Abstract Reactions involving carbon in the deep Earth have limited manifestations on Earth's surface, yet they have played a critical role in the evolution of our planet. The metal-silicate partitioning reaction promoted carbon capture during Earth's accretion and may have sequestered substantial carbon in Earth's core. The freezing reaction involving iron-carbon liquid could have contributed to the growth of Earth's inner core and the geodynamo. The redox melting/freezing reaction largely controls the movement of carbon in the modern mantle, and reactions between carbonates and silicates in the deep mantle also promote carbon mobility. The 10-year activity of the Deep Carbon Observatory has made important contributions to our knowledge of how these reactions are involved in the cycling of carbon throughout our planet, both past and present, and has helped to identify gaps in our understanding that motivate and give direction to future studies.